The Principles of Psychology is the founding systematic account of the human mind in English. James spent twelve years writing it, drawing on German experimental psychology, physiology, philosophy, and introspection, aiming to treat psychology as a natural science while insisting that the living stream of experience could not be reduced to reflex arcs and laboratory measurements alone.
Volume I opens with the brain and nervous system, then turns to the phenomena that most interested James. The chapter on Habit argues that the plasticity of nervous tissue means every repeated act carves its path more deeply, eventually running without conscious supervision. James draws the practical moral plainly: early in life, make as many useful behaviors as possible automatic, and guard against forming bad ones, because by the age of thirty character has 'set like plaster.'
The chapter on the Stream of Thought, later called the stream of consciousness, is James's most influential contribution. He attacks the prevailing British empiricist picture of the mind as a mosaic of discrete sensations linked by association. Consciousness, he argues, never appears to itself as a chain or train; it flows. No sensation recurs unmodified; every thought is personal and unique; and consciousness carries with it a fringe of relations (vague feelings of 'and,' 'but,' 'if,' and tendency) that logic and language can barely capture. The Consciousness of Self follows, distinguishing the material self (body, clothes, family, property), the social self (the recognition one receives from others), the spiritual self (one's inner dispositions), and the pure Ego.
Volume I also contains the chapter on Attention, where James defines it as the mind's selective, voluntary focusing on one object at the expense of others. This is not a passive faculty but an active one: interest shapes experience. The lengthy chapters on Perception, Memory, Imagination, and Reasoning round out the cognitive architecture of the book.
Volume II moves from cognition into action and feeling. The Emotions chapter introduces the James-Lange theory: the standard view that an emotion causes the body to react is reversed. The bodily changes, the racing heart, the tensed muscles, the tears, come first, triggered directly by perception; the emotional feeling is our awareness of those changes as they occur. The final major chapter on Will argues that voluntary action is always preceded by an idea of the movement to be performed, derived from previous involuntary experience. Willing is not some separate power imposed on the body; it is the mind consenting to act on whichever idea presently occupies the field of attention. Together the two volumes constitute the first comprehensive psychology of the normal adult mind.